Geochemistry and petrography of impact breccias and target rocks from the 145 Ma Morokweng impact structure, South Africa     

Christian Koeberl  Wolf Uwe reimold 《Geochimica et cosmochimica acta》2003,67(10):1837-1862

Morokweng is a large, 145 Ma impact structure in the Northwest Province of South Africa. The impact origin of this structure and its melt rock has been confirmed by ample evidence of shock metamorphism in clasts within the melt rock and samples from granitoid basement below the melt body. The age of this structure is indistinguishable from the biostratigraphic age of the Jurassic-Cretaceous (J-K) boundary. The size of Morokweng, for which diameters ranging from 70 to 165 kilometers have been quoted before, and which has important implications regarding its relation to the J-K boundary, remains an open question.Here we present new results of a detailed petrographic and chemical investigation of impact melt rock and country rock samples. The granophyric melt rock is mostly unaltered and contains a large number of gabbroic and felsic clasts. The occurrence of baddeleyite, formed from high-temperature dissociation of primary zircon, indicates a high-temperature origin. The impact melt rock body, which in the cores investigated here has a thickness of at least 120 m, shows no statistically significant variation or trend in chemical composition with depth or geographic location. Chemical data for impact melt rock, breccia dike/vein breccia samples, granite, quartzite, and basic to mafic clasts were used in harmonic least squares mixing calculations to determine the source rock types and their proportions involved in the formation of the impact melt rock. Granite is the dominant target rock component (50 to 63% by weight; depending on target composition input to the mixing models), with significant (35 to 50%) mafic contributions, and a (possible) minor contribution of quartzite. New platinum group element (Ru, Rh, Pd, Os, Ir, and Pt), Re, and Au data, as well as data for other siderophile elements (Cr, Co, Ni, and Ir), confirm the presence of up to ∼ 5% of a chondritic component in the melt rock. The indigenous contribution of the PGEs from the target rocks is negligible. Normalized PGE abundance patterns and interelement ratios of Morokweng impact melt rock indicate that the projectile was likely of ordinary chondritic (possibly L chondrite) composition, but the choice of the meteoritic compositional data influences this interpretation.  相似文献   

Climatic significance of seasonal trace element and stable isotope variations in a modern freshwater tufa   总被引：1，自引：0，他引：1  

Christian Ihlenfeld  Marc D. Norman  Russell N. Drysdale  John Webb 《Geochimica et cosmochimica acta》2003,67(13):2341-2357

We present a continuous ∼14-yr-long (1985 to 1999) high-resolution record of trace element (Mg, Sr, Ba, U) and stable isotope (δ¹³C, δ¹⁸O) variations in a modern freshwater tufa from northwestern Queensland, Australia. By utilizing the temperature dependence of the δ¹⁸O signal, an accurate chronology was developed for the sampled profile, which allowed a comparison of the chemical records with hydrological and meteorological observations. As a consequence, it was possible to constrain the relevant geochemical processes relating climate variables, such as temperature and precipitation, to their chemical proxies in the tufa record. Temperatures calculated from the Mg concentrations of the tufa samples provide close approximations of average annual water temperature variations. Furthermore, we demonstrate that temporal changes in (Mg/Ca)_water can be estimated using an empirically derived equation relating (Mg/Ca)_water to the (Sr/Ba) ratio measured in the tufa samples. By means of this relationship, it is theoretically possible to determine the (Mg/Ca) ratio of paleowaters, and hence to derive reliable estimates of former water temperatures from the Mg concentrations of fossil tufas from the study area. Sympathetic variations in Sr, Ba, and δ¹³C along the sampled profile record changes in water chemistry, which are most probably caused by variable amounts of calcite precipitation within the vadose zone of the karst aquifer. This process is thought to be markedly subdued whenever the amount of wet-season precipitation exceeds a given threshold. Accordingly, distinct minima in Sr, Ba, and δ¹³C are interpreted to reflect years with above-average rainfall. The pronounced seasonal and annual variability of the U concentration along the profile is thought to primarily record changes in the U flux from the soil to the water table. We suggest that during intensive rain events U is transported to the phreatic zone by complexing organic colloids, giving rise to conspicuous U maxima in the tufa after above-average wet seasons. This study demonstrates the potential of freshwater tufas to provide valuable information on seasonal temperature and rainfall variations. If tufa deposits turn out to be reasonably resistant to secondary processes, combined investigation of speleothems and tufas from the same area could become a promising approach in future research. While speleothems offer continuous records of long-term paleoenvironmental changes, tufas could provide high-resolution time windows into selected periods of the past.  相似文献   

Control of sulfate pore-water profiles by sedimentary events and the significance of anaerobic oxidation of methane for the burial of sulfur in marine sediments     

Christian Hensen  Matthias Zabel  Tilmann Schwenk  Natascha Riedinger  Antje Boetius 《Geochimica et cosmochimica acta》2003,67(14):2631-2647

Gravity driven mass-flow deposits proven by sedimentary and digital echosounder data are indicative for prevailing dynamic sedimentary conditions along the continental margin of the western Argentine Basin. In this study we present geochemical data from a total of 23 gravity cores. Pore-water SO₄ is generally depleted within a few meters below the sediment surface by anaerobic oxidation of methane (AOM). The different shapes of SO₄ profiles (concave, kink- and s-type) can be consistently explained by sedimentary slides possibly in combination with changes in the CH₄ flux from below, thus, mostly representing transient pore-water conditions. Since slides may keep their original sedimentary signature, a combined analysis and numerical modeling of geochemical, physical properties, and hydro acoustic data could be applied in order to reconstruct the sedimentary history. We present first order estimates of the dating of sedimentary events for an area where conventional stratigraphic methods failed to this day. The results of the investigated sites suggest that present day conditions are the result of events that occurred decades to thousands of years ago and promote a persisting mass transport from the shelf into the deep-sea, depositing high amounts of reactive compounds. The high abundance of reactive iron phases in this region maintains low hydrogen sulfide levels in the sediments by a nearly quantitative precipitation of all reduced sulfate by AOM. For the total region we estimate a SO₄ (or CH₄) flux of 6.6 × 10¹⁰ moles per year into the zone of AOM. Projected to the global continental slope and rise area, this may sum up to about 2.6 × 10¹² moles per year. Provided that the sulfur is completely fixed in the sediments it is about twice the global value of the recent global sulfur burial in marine sediments of 1.2 × 10¹² moles per year as previously estimated. Thus, AOM obviously contributes very significantly to the regulation of global sulfur reservoirs, which is hitherto not sufficiently recognized. This finding may have implications for global geochemical models, as sulfur burial is an important control factor in the development of atmospheric oxygen levels over time.  相似文献   

9000 years of geochemical evolution of lithogenic major and trace elements in the sediment of an alpine lake – the role of climate, vegetation, and land-use history     

Karin A. Koinig  William Shotyk  André F. Lotter  Christian Ohlendorf  Michael Sturm 《Journal of Paleolimnology》2003,30(3):307-320

A 9000cal. year record of geochemistry was analysed in a sediment core obtained from a Swiss alpine hard-water lake (1937 ma.s.l.) that is located at the present-day tree-line. Geochemical stratigraphies are compared to changes in mineralogy, grain-size, pollen, and macrofossil records. This allows the reconstruction of the effects of changes in vegetation and of 3500 years of land-use in the catchment area on sediment geochemistry. Using principal component analysis, two major geochemical groups are distinguished: (i) Changes in concentrations of Rb, Ti, Zr, Fe, As, and Pb are closely related to corresponding changes in the concentrations of quartz and clay. They are thus considered to represent the silicate fraction which shows an increase from the oldest to the youngest core section. (ii) In contrast, Ca and Sr concentrations are positively correlated with changes in silt, sand, and calcite. They are therefore considered to represent the carbonate fraction which gradually decreased. Based on constrained cluster analysis, the core is divided into two major zones. The oldest zone (A; 9000–6400 cal.BP) is characterised by high concentrations of detrital carbonates. The more open catchment vegetation at that time promoted the physical weathering of these carbonates. The second major zone (B, 6400 cal.BP–1996 AD) is divided into four subsections with boundaries at ca. 3500, 2400, and 160cal. BP. The lower part of this zone, B1, is characterized by a gradual decrease in the carbonate-silt fraction and a pronounced increase in the silicate-clay fraction. This is concurrent with the expansion of Picea in the catchment area, which probably stabilized the soil. The middle part, B2 and B3 (3500–160cal. BP), comprises pronounced fluctuations in all elements, especially Ca, Sr, Mn, and Rb, but also in clay and silt. These changes are related to varying intensities of alpine farming. In the same section, Mn/Fe ratios are highly variable, suggesting changes in the mixing regime of the lake with phases of anoxic bottom water. The uppermost section, B4 (since 160cal. BP), is characterized by a steep decline in the silicate fraction and an increase in Ca and Sr. Despite the decrease in the silicate fraction, Pb increases, due to elevated atmospheric input resulting from early metal pollution, are masked by the high natural variability. Generally, changes in vegetation, which correspond to climate changes in the early Holocene and to human activities since ca. 3700cal. BP, are the controlling factor for variations in the geochemical composition of the sediment of Sägistalsee.  相似文献   

Distribution patterns and habitat characterization of Simuliidae (Insecta: Diptera) in a low-order sandstone stream (Weidlingbach, Lower Austria)     

Christian Scheder  Johann A. Waringer   《Limnologica》2002,32(3)

A total of 1504 larval and 31 pupal Simuliidae were caught from March 2000 to February 2001 at the Weidlingbach, a fourth order tributary of the Danube near Vienna, Austria, using a modified box sampler (sampling area = 2116 cm²) at 12 sampling stations from source to mouth. From the six species collected, Prosimulium tomosvaryi (Enderlein) and two species of the Simulium ornatum-group (S. trifasciatum Curtis and S. ornatum Meigen) accounted for 97.5% of the total. Based on head width, instars 1–7 were collected in the S. ornatum-group and instars 2–7 in P. tomosvaryi; from two of the remaining species [Simulium (Nevermannia) cryophilum (Rubzov) and S. (N.) vernum Macquart], only pupae were sampled. The S. ornatum-group was most abundant on coarse substrates (median = 55.9 mm) exposed to high water velocity (median = 55.9 cm/s; range = 9–83 cm/s); the latter was also true for P. tomosvaryi although it favoured smaller sediment grain sizes (median = 32.4 mm). Species richness and population density increased from source to mouth. At sampling sites near the source Simuliidae were completely lacking. In headwaters only P. tomosvaryi was present, whereas the S. ornatum-group and Simulium (Simulium) argyreatum Meigen was collected exclusively near the mouth.  相似文献   

The indication of morphological degradation of streams and rivers using Simuliidae     

Christian K. Feld  Ellen Kiel  Melanie Lautenschlger 《Limnologica》2002,32(3)

Blackfly communities from five German stream types out of two ecoregions (small and mid-sized siliceous gravel-bed mountain streams of the Central mountains, ecoregion 9, and organic type brooks, small and mid-sized sand-bottomed Central lowland streams of ecoregion 14) are compared. Ecoregional, as well as stream type-specific biocoenotic differences are discussed. The presence of Prosimulium sp. was restricted to mountain streams, whereas Simulium lineatum seemed to prefer mid-sized sand-bottomed Central lowland streams, and S. vernum showed a clear preference for Central lowland streams. An Index of Morphological Stress (IMS), derived from 22 geo-hydromorphological parameters recorded during sampling in the field, is presented. According to the IMS values, sites are divided into morphologically ‘unstressed’ sites (high or good morphological quality) and ‘stressed’ sites (moderate, poor or bad morphological quality), and biocoenotic differences of the two categories are discussed. Two stream types and the entire data set showed significantly higher numbers of taxa at ‘unstressed’ sites. Linear Multiple Regression (LMR) was used to identify geo-hydromorphological parameters that significantly explain the variance of the three most constant taxa, Prosimulium sp., P. hirtipes and Simulium sp. in the LMR model.  相似文献   

The stability of osumilite in high grade metamorphic rocks     

B. J. Hensen 《Contributions to Mineralogy and Petrology》1977,64(2):197-204

Osumilite, approximate composition K(Mg,Fe)₂ Al₅Si₁₀O₃₀, has been reported recently from two granulite localities. The mineral has been synthesised in a model pelitic composition at 1000 and 1100 ° C and 3.6–6.3 kb under conditions of low water and oxygen fugacity. Osumilite coexists, apparently stably, with hypersthene, cordierite and quartz (?) thus duplicating the mineral assemblage of one of the natural occurrences. Osumilite is in a divariant reaction relationship with cordierite and hypersthene i.e. osumilite ? cordierite + hypersthene + orthoclase+quartz. This reaction runs to the right with increasing pressure. Experimental data and field observations suggest that the joins osumilite-garnet and osumilite-sillimanite are not stable. It is suggested osumilite is involved in an invariant point in the system K₂O-MgO-FeO-A1₂O₃-SiO₂ with the phases cordierite, hypersthene, sapphirine, spinel, orthoclase and quartz. The invariant point should occur at 1000 ± 100 °C and 7± 2kb.  相似文献   

Une méthode de simulation de l'évolution des profils d'altération     

Christian Fouillac  Gil Michard  Gérard Bocquier 《Geochimica et cosmochimica acta》1977,41(2):207-213

Calculations of transfer of elements between minerals and aqueous solutions can be extended to water open systems. With this method, we can obtain steady state for water composition. Furthermore, evolution in space and time of a weathering profile can be computed.  相似文献   

Paleoclimatic record of a long deep sea core from the eastern Mediterranean     

Maria Bianca Cita  Colette Vergnaud-Grazzini  Christian Robert  Hervé Chamley  Neri Ciaranfi  Sara d&#x;Onofrio 《Quaternary Research》1977,8(2):205-235

A deep-sea core over 16 m long from the crestal area of the Mediterranean Ridge has been investigated with different techniques, including quantitative micropaleontology, stable isotopes (measured on the epipelagic species Globigerinoides ruber and on the mesopelagic species Globorotalia inflata), and clay mineralogy. The resulting record of climatic fluctuations can be cross correlated to other Mediterranean cores by means of isochronous lithologies (tephra layers and sapropels). The climatic record of the Mediterranean is similar in character, phase, and chronology to the records investigated in the equatorial Pacific and in the Caribbean. Isotope stages 1 to 17 have been recognized. Cyclically repeated stagnant cycles resulting in sapropel deposition complicate both the isotopic and the faunal signal. The isotopic investigations reveal that the temperature change in the surface layers of the eastern Mediterranean was no greater than 8°C in the late “glacial” Pleistocene. The chronostratigraphic and biostratigraphic interpretation of Core KS09 indicate that the mean sedimentation rate was 2.4 cm/1000 years, a value very close to the 2.5 cm/1000 years calculated for the entire Quaternary section at DSDP Site 125, also located in the crestal area of the Mediterranean Ridge in the Ionian Basin. The base of KS09 is likely to be very close to the Brunhes/Matuyama boundary dated at 0.7 my.  相似文献   

Notiz zur Phagotrophie einerSpumella-Art (Chrysophyceae) im Walchensee     

Dr. Christian Steinberg 《Aquatic Sciences - Research Across Boundaries》1980,42(1):72-77

Monophagy ofSpumella sp. Cienkowsky (1870) (Chrysophyceae) from the mesotrophic Lake Walchensee was postulated by ecological data and supported by microphotographs. In this lakeSpumella sp. feeds on the nannoplanktic diatomCyclotella glomerata.  相似文献